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After a wildfire event, ash is a newly formed surficial soil layer with microscale properties such as roughness, morphology, and chemical composition that may impact how ashes form fabrics in situ and so affect the overall hydrological conditions of a burned area (infiltration capacity, permeability, etc.). To examine the effects of ash microscale properties on macroscale behavior, eight wildfire ash samples from California were characterized physically (specific gravity, specific surface area, particle size, etc.), chemically (elemental composition, organic and inorganic carbon content, etc.), and geotechnically (strength, compaction, saturated hydraulic conductivity, etc.). The tested ashes were found to contain predominantly organic unburned carbons and carbonates derived from the combustion of calcium-oxalate rich fuels in temperatures likely ranging from 300°C to 500°C. Ashes had high specific surface areas because morphologically, particles had highly texturized and porous surfaces. Additional water was necessary to coat the particle surfaces, which led to high liquid limits and compaction optimum moisture contents. Hydraulic conductivity values were within range for silty sands (10^−5–10^−3  cm/s), and specimens had friction angles near 30°. However, tested ashes consistently demonstrated high void ratios and low bulk densities during testing for strength, hydraulic conductivity, and compaction. These anomalies were attributed to unusual carbonate morphologies; the high interparticle friction of these phases allowed ashes to form looser fabrics than a typical silty sand and contributed to the measured high void ratios, low maximum dry unit weights, and high friction angles. Overall, we hypothesize that the relative amounts of inorganic versus organic constituents in our wildfire ash samples affected how the ashes formed fabrics and so affected their geotechnical properties.